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Accepted name: (
S)-3,5-dihydroxyphenylglycine + 2-oxoglutarate = 2-(3,5-dihydroxyphenyl)-2-oxoacetate + L-glutamate
S)-3,5-dihydroxyphenylglycine = (2 S)-2-amino-2-(3,5-dihydroxyphenyl)acetic acid
Other name(s): HpgT
Systematic name: (
Comments: A pyridoxal-5′-phosphate protein. The enzyme from the bacterium
Amycolatopsis orientalis catalyses the reaction in the reverse direction as part of the biosynthesis of the ( S)-3,5-dihydroxyphenylglycine constituent of the glycopeptide antibiotic chloroeremomycin.
Links to other databases:
BRENDA, EXPASY, KEGG, MetaCyc
Sandercock, A.M., Charles, E.H., Scaife, W., Kirkpatrick, P.N., O'Brien, S.W., Papageorgiou, E.A., Spencer, J.B. and Williams, D.H. Biosynthesis of the di-meta-hydroxyphenylglycine constituent of the vancomycin-group antibiotic chloroeremomycin.
Chem. Comm. (2001) 1252–1253.
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