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Your query returned 1 entry. 
Printable version
| EC | 2.5.1.159 | ||
| Accepted name: | hapalindole G dimethylallyltransferase | ||
| Reaction: | (1) prenyl diphosphate + hapalindole G = ambiguine A + diphosphate (2) prenyl diphosphate + hapalindole U = ambiguine H + diphosphate |
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| For diagram of hapalindole/fischerindole biosynthesis, click here | |||
| Glossary: | prenyl diphosphate = dimethylallyl diphosphate hapalindole G = (6aS,8R,9R,10R,10aS)-8-chloro-10-isocyano-6,6,9-trimethyl-9-vinyl-2,6,6a,7,8,9,10,10a-octahydronaphtho[1,2,3-cd]indole ambiguine A = (6aS,8R,9R,10R,10aS)-8-chloro-10-isocyano-6,6,9-trimethyl-1-(2-methylbut-3-en-2-yl)-9-vinyl-2,6,6a,7,8,9,10,10a-octahydronaphtho[1,2,3-cd]indole hapalindole U = (6aS,9R,10R,10aS)-10-isocyano-6,6,9-trimethyl-9-vinyl-2,6,6a,7,8,9,10,10a-octahydronaphtho[1,2,3-cd]indole ambiguine H = (6aS,9R,10R,10aS)-9-ethenyl-10-isocyano-6,6,9-trimethyl-1-(2-methylbut-3-en-2-yl)-2,6,6a,7,8,9,10,10a-octahydronaphtho[1,2,3-cd]indole |
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| Other name(s): | ambP3 (gene name); famD1 (gene name) | ||
| Systematic name: | prenyl-diphosphate:hapalindole G prenyltransferase (ambiguine A-forming) | ||
| Comments: | Requires Mg2+. The enzyme, characterized from the cyanobacterium Fischerella ambigua UTEX 1903, is involved in the biosynthesis of hapalindole-type alkaloids. | ||
| Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc | ||
| References: |
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