EC |
1.1.1.199 |
Accepted name: |
(S)-usnate reductase |
Reaction: |
(6R)-2-acetyl-6-(3-acetyl-2,4,6-trihydroxy-5-methylphenyl)-3-hydroxy-6-methyl-2,4-cyclohexadien-1-one + NAD+ = (S)-usnate + NADH + H+ |
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For diagram of reaction, click here |
Glossary: |
reduced (S)-usnate = reduced (-)-usnate = (6R)-2-acetyl-6-(3-acetyl-2,4,6-trihydroxy-5-methylphenyl)-3-hydroxy-6-methyl-2,4-cyclohexadien-1-one |
Other name(s): |
L-usnic acid dehydrogenase |
Systematic name: |
reduced-(S)-usnate:NAD+ oxidoreductase (ether-bond-forming) |
Links to other databases: |
BRENDA, EXPASY, KEGG, MetaCyc, CAS registry number: 77237-99-1 |
References: |
1. |
Estevéz, M.P., Legaz, E., Olmeda, L., Pérez, F.J. and Vincente, C. Purification and properties of a new enzyme from Evernia prunastri, which reduces L-usnic acid. Z. Naturforsch. C: Biosci. 36 (1981) 35–39. |
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[EC 1.1.1.199 created 1984] |
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