The Enzyme Database

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Accepted name: flavonol-3-O-glucoside glucosyltransferase
Reaction: UDP-glucose + a flavonol 3-O-β-D-glucoside = UDP + a flavonol 3-O-β-D-glucosyl-(1→2)-β-D-glucoside
For diagram of kaempferol-glycoside biosynthesis, click here and for diagram of the biosynthesis of quercetin 3-O-triglucoside, click here
Other name(s): UDP-glucose:flavonol-3-O-glucoside 2′′-O-β-D-glucosyltransferase
Systematic name: UDP-glucose:flavonol-3-O-β-D-glucoside 2′′-O-β-D-glucosyltransferase
Comments: One of three specific glucosyltransferases in pea (Pisum sativum) that successively add a β-D-glucosyl group first to O-3 of kaempferol, and then to O-2 of the previously added glucosyl group giving the 3-O-sophoroside and then the 3-O-sophorotrioside (see also EC, flavonol 3-O-glucosyltransferase and EC, flavonol-3-O-glycoside glucosyltransferase). TDP-glucose can replace UDP-glucose as the glucose donor but the reaction proceeds more slowly.
Links to other databases: BRENDA, EXPASY, KEGG, MetaCyc
1.  Jourdan, P.S. and Mansell, R.L. Isolation and partial characterization of three glucosyl transferases involved in the biosynthesis of flavonol triglucosides in Pisum sativum L. Arch. Biochem. Biophys. 213 (1982) 434–443. [DOI] [PMID: 6462109]
[EC created 2004]

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