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Your query returned 1 entry. Printable version
EC | 1.14.14.141 | ||
Accepted name: | psoralen synthase | ||
Reaction: | (+)-marmesin + [reduced NADPH—hemoprotein reductase] + O2 = psoralen + [oxidized NADPH—hemoprotein reductase] + acetone + 2 H2O | ||
For diagram of reaction, click here | |||
Glossary: | (+)-marmesin = (S)-2-(2-hydroxypropan-2-yl)-2,3-dihydro-7H-furo[3,2-g]chromen-7-one psoralen = 7H-furo[3,2-g]chromen-7-one |
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Other name(s): | CYP71AJ1 | ||
Systematic name: | (+)-marmesin,[reduced NADPH—hemoprotein reductase]:oxygen oxidoreductase | ||
Comments: | This microsomal cytochrome P-450 (heme-thiolate) enzyme is rather specific for (+)-marmesin, although it can also accept 5-hydroxymarmesin to a much lesser extent. Furanocoumarins protect plants from fungal invasion and herbivore attack. (+)-Columbianetin, the angular furanocoumarin analogue of the linear furanocoumarin (+)-marmesin, acts as a competitive inhibitor even though it is not a substrate. | ||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc | ||
References: |
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