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Your query returned 3 entries. Printable version
EC | 1.14.14.161 | ||||
Accepted name: | nepetalactol monooxygenase | ||||
Reaction: | (+)-cis,trans-nepetalactol + 3 [reduced NADPH—hemoprotein reductase] + 3 O2 = 7-deoxyloganetate + 3 [oxidized NADPH—hemoprotein reductase] + 4 H2O (overall reaction) (1a) (+)-cis,trans-nepetalactol + [reduced NADPH—hemoprotein reductase] + O2 = 7-deoxyloganetic alcohol + [oxidized NADPH—hemoprotein reductase] + H2O (1b) 7-deoxyloganetic alcohol + [reduced NADPH—hemoprotein reductase] + O2 = iridotrial + [oxidized NADPH—hemoprotein reductase] + 2 H2O (1c) iridotrial + [reduced NADPH—hemoprotein reductase] + O2 = 7-deoxyloganetate + [oxidized NADPH—hemoprotein reductase] + H2O |
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For diagram of gibberellin A12 biosynthesis, click here | |||||
Glossary: | (+)-cis,trans-nepetalactol = (4aS,7S,7aR)-4,7-dimethyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-1-ol 7-deoxyloganetate = (1S,4aS,7S,7aR)-1-hydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-4-carboxylate |
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Other name(s): | CYP76A26 (gene name); iridoid oxidase (misleading) | ||||
Systematic name: | (+)-cis,trans-nepetalactol,[reduced NADPH—hemoprotein reductase]:oxygen oxidoreductase (hydroxylating) | ||||
Comments: | The enzyme, characterized from the plant Catharanthus roseus, is a cytochrome P-450 (heme thiolate) protein. It catalyses three successive reactions in the pathway leading to biosynthesis of monoterpenoid indole alkaloids. | ||||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc | ||||
References: |
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EC | 2.4.1.323 | ||||
Accepted name: | 7-deoxyloganetic acid glucosyltransferase | ||||
Reaction: | UDP-α-D-glucose + 7-deoxyloganetate = UDP + 7-deoxyloganate | ||||
For diagram of secologanin biosynthesis, click here | |||||
Other name(s): | UGT8 | ||||
Systematic name: | UDP-α-D-glucose:7-deoxyloganetate O-D-glucosyltransferase | ||||
Comments: | Isolated from the plant Catharanthus roseus (Madagascar periwinkle). Involved in loganin and secologanin biosynthesis. Does not react with 7-deoxyloganetin. cf. EC 2.4.1.324 7-deoxyloganetin glucosyltransferase. | ||||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc | ||||
References: |
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EC | 2.4.1.324 | ||||
Accepted name: | 7-deoxyloganetin glucosyltransferase | ||||
Reaction: | UDP-α-D-glucose + 7-deoxyloganetin = UDP + 7-deoxyloganin | ||||
For diagram of secologanin biosynthesis, click here | |||||
Other name(s): | UDPglucose:iridoid glucosyltransferase; UGT6; UGT85A24 | ||||
Systematic name: | UDP-α-D-glucose:7-deoxyloganetin O-D-glucosyltransferase | ||||
Comments: | Isolated from the plants Catharanthus roseus (Madagascar periwinkle) and Gardenia jasminoides (cape jasmine). With Gardenia it also acts on genipin. Involved in loganin and secologanin biosynthesis. Does not react with 7-deoxyloganetate. cf. EC 2.4.1.323 7-deoxyloganetic acid glucosyltransferase. | ||||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc | ||||
References: |
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