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Your query returned 2 entries. Printable version
EC | 1.14.11.35 | ||||
Accepted name: | 1-deoxypentalenic acid 11β-hydroxylase | ||||
Reaction: | 1-deoxypentalenate + 2-oxoglutarate + O2 = 1-deoxy-11β-hydroxypentalenate + succinate + CO2 | ||||
For diagram of pentalenolactone biosynthesis, click here | |||||
Glossary: | 1-deoxypentalenate = (1R,3aR,5aS,8aR)-1,7,7-trimethyl-1,2,3,3a,5a,6,7,8-octahydrocyclopenta[c]pentalene-4-carboxylate 1-deoxy-11β-hydroxypentalenate = (1S,2R,3aR,5aS,8aR)-2-hydroxy-1,7,7-trimethyl-1,2,3,3a,5a,6,7,8-octahydrocyclopenta[c]pentalene-4-carboxylate |
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Other name(s): | ptlH (gene name); sav2991 (gene name); pntH (gene name) | ||||
Systematic name: | 1-deoxypentalenic acid,2-oxoglutarate:oxygen oxidoreductase | ||||
Comments: | The enzyme requires iron(II) and ascorbate. Isolated from the bacterium Streptomyces avermitilis. Part of the pathway for pentalenolactone biosynthesis. | ||||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc, PDB | ||||
References: |
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EC | 1.14.15.11 | ||||
Accepted name: | pentalenic acid synthase | ||||
Reaction: | 1-deoxypentalenate + reduced ferredoxin + O2 = pentalenate + oxidized ferredoxin + H2O | ||||
For diagram of pentalenolactone biosynthesis, click here | |||||
Glossary: | 1-deoxypentalenate = (1R,3aR,5aS,8aR)-1,7,7-trimethyl-1,2,3,3a,5a,6,7,8-octahydrocyclopenta[c]pentalene-4-carboxylate pentalenate = (1R,3aR,5aS,6R,8aS)-6-hydroxy-1,7,7-trimethyl-1,2,3,3a,5a,6,7,8-octahydrocyclopenta[c]pentalene-4-carboxylate |
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Other name(s): | CYP105D7; sav7469 (gene name); 1-deoxypentalenate,reduced ferredoxin:O2 oxidoreductase | ||||
Systematic name: | 1-deoxypentalenate,reduced ferredoxin:oxygen oxidoreductase | ||||
Comments: | A heme-thiolate enzyme (P-450). Isolated from the bacterium Streptomyces avermitilis. The product, pentalenate, is a co-metabolite from pentalenolactone biosynthesis. | ||||
Links to other databases: | BRENDA, EXPASY, KEGG, MetaCyc, PDB | ||||
References: |
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