The Enzyme Database

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EC 2.4.1.195     
Accepted name: N-hydroxythioamide S-β-glucosyltransferase
Reaction: UDP-glucose + N-hydroxy-2-phenylethanethioamide = UDP + desulfoglucotropeolin
For diagram of glucotropeolin biosynthesis, click here
Other name(s): desulfoglucosinolate-uridine diphosphate glucosyltransferase; uridine diphosphoglucose-thiohydroximate glucosyltransferase; thiohydroximate β-D-glucosyltransferase; UDPG:thiohydroximate glucosyltransferase; thiohydroximate S-glucosyltransferase; thiohydroximate glucosyltransferase; UDP-glucose:thiohydroximate S-β-D-glucosyltransferase
Systematic name: UDP-glucose:N-hydroxy-2-phenylethanethioamide S-β-D-glucosyltransferase
Comments: Involved with EC 2.8.2.24, desulfoglucosinolate sulfotransferase, in the biosynthesis of thioglucosides in cruciferous plants.
Links to other databases: BRENDA, EXPASY, KEGG, MetaCyc, CAS registry number: 9068-14-8
References:
1.  Jain, J.C., Reed, D.W., Groot Wassink, J.W.D. and Underhill, E.W. A radioassay of enzymes catalyzing the glucosylation and sulfation steps of glucosinolate biosynthesis in Brassica species. Anal. Biochem. 178 (1989) 137–140. [PMID: 2524977]
2.  Reed, D.W., Davin, L., Jain, J.C., Deluca, V., Nelson, L. and Underhill, E.W. Purification and properties of UDP-glucose:thiohydroximate glucosyltransferase from Brassica napus L. seedlings. Arch. Biochem. Biophys. 305 (1993) 526–532. [PMID: 8373190]
3.  Fahey, J.W., Zalcmann, A.T. and Talalay, P. The chemical diversity and distribution of glucosinolates and isothiocyanates among plants. Phytochemistry 56 (2001) 5–51. [PMID: 11198818]
4.  Grubb, C.D., Zipp, B.J., Ludwig-Müller, J., Masuno, M.N., Molinski, T.F. and Abel, S. Arabidopsis glucosyltransferase UGT74B1 functions in glucosinolate biosynthesis and auxin homeostasis. Plant J. 40 (2004) 893–908.
[EC 2.4.1.195 created 1992, modified 2006]
 
 


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