The Enzyme Database

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EC 2.3.1.152     
Accepted name: alcohol O-cinnamoyltransferase
Reaction: 1-O-trans-cinnamoyl-β-D-glucopyranose + ROH = alkyl cinnamate + glucose
Systematic name: 1-O-trans-cinnamoyl-β-D-glucopyranose:alcohol O-cinnamoyltransferase
Comments: Acceptor alcohols (ROH) include methanol, ethanol and propanol. No cofactors are required as 1-O-trans-cinnamoyl-β-D-glucopyranose itself is an "energy-rich" (activated) acyl-donor, comparable to CoA-thioesters. 1-O-trans-Cinnamoyl-β-D-gentobiose can also act as the acyl donor, but with much less affinity.
Links to other databases: BRENDA, EXPASY, KEGG, MetaCyc, CAS registry number: 203009-15-8
References:
1.  Mock, H.-P., Strack, D. Energetics of uridine 5′-diphosphoglucose-hydroxy-cinnamic acid acyl-glucotransferase reaction. Phytochemistry 32 (1993) 575–579.
2.  Latza, S., Gansser, D., Berger, R.G. Carbohydrate esters of cinnamic acid from fruits of Physalis peruviana, Psidium guajava and Vaccinium vitis IDAEA. Phytochemistry 43 (1996) 481–485.
[EC 2.3.1.152 created 1999]
 
 


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