ExplorEnz: EC 1.14.14.66

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1.14.14.66

Accepted name:

marmesin synthase

Reaction:

demethylsuberosin + [reduced NADPH—hemoprotein reductase] + O₂ = (+)-marmesin + [oxidized NADPH—hemoprotein reductase] + H₂O

For diagram of psoralen biosynthesis, click here

Glossary:

demethylsuberosin = 7-hydroxy-6-prenyl-1-benzopyran-2-one
(+)-marmesin = (S)-2-(2-hydroxypropan-2-yl)-2,3-dihydro-7H-furo[3,2-g]chromen-7-one

Systematic name:

demethylsuberosin,[reduced NADPH—hemoprotein reductase]:oxygen oxidoreductase

Comments:

A P-450 monoxygenase involved in psoralen biosynthesis, see EC 1.14.13.102, psoralen synthase.

Links to other databases:

BRENDA, EXPASY, KEGG, MetaCyc

References:

1.	Hamerski, D. and Matern, U. Elicitor-induced biosynthesis of psoralens in Ammi majus L. suspension cultures. Microsomal conversion of demethylsuberosin into (+)marmesin and psoralen. Eur. J. Biochem. 171 (1988) 369–375. [PMID: 2828055]

[EC 1.14.14.66 created 2018]